Memory effects across surfactant mesophases.

On the Swelling of Bicontinuous Lyotropic Mesophases

The swelling of sponge-like bicontinuous mesophases of bilayers of surfactant (or lipid) in water as a function of dilution is analyzed. Analytic formulae for the swelling are derived assuming ii) constant aggregate thickness and (it) fixed surface area per surfactant molecule at an imaginary surface located within the bilayer. Approximate swelling laws are derived for bicontinuous films and co...

Conducting polymer nanofibers with controlled diameters synthesized in hexagonal mesophases

Oil-swollen hexagonal mesophases resulting from the surfactant mediated self-assembly of a quaternary mixture of water, surfactant, co-surfactant, and oil, are versatile templates to synthesize anisotropic nanomaterials. Poly(diphenylbutadyine) (PDPB) polymer nanofibrous network structures were produced in the oil tubes of the mesophases by photo-induced radical polymerization using a chemical ...

Molecularly ordered inorganic frameworks in layered silicate surfactant mesophases.

Self-assembled lamellar silica-surfactant mesophase composites have been prepared with crystal-like ordering in the silica frameworks using a variety of cationic surfactant species under hydrothermal conditions. These materials represent the first mesoscopically ordered composites that have been directly synthesized with structure-directing surfactants yielding highly ordered inorganic framewor...

Transitions between mesophases involving cubic phases in the surfactant-water systems. Epitaxial relations and their consequences in a geometrical framework

Surfactant mesophases mediated by colloidal particles

We have investigated effects of guest colloidal particles on the mesoscopic structures of a surfactant/water system by means of small angle neutron and x-ray scattering techniques. The addition of a small amount of colloidal particles between lamellar slits reduces the undulational fluctuations of lamellae and brings about a lamellar to micelle transition. On the other hand, on addition of coll...